These four expressions are a common source of confusion for German learners. The reason is that “Morgen” can be either a noun or an adverb, and the meaning depends on capitalization. ”Der Morgen” (with the capital “M”) means “the morning”, e.g.
It was a nice morning.
The most common expression with “der Morgen”, apart from “guten Morgen” = “good morning”, is ”am Morgen”, meaning “in the morning”:
The train will leave in the morning at 9 o’clock.
Where it is understood from the context which morning is meant. If we want to express that something happens repeatedly, we have to use the adverb ”morgens” (note the small “m”) which literally means “mornings”:
Mornings, I must [go] to work.
This construction doesn’t sound quite right in English, but it’s fine in German. We can also use ”jeden Morgen” = “every morning”.
I drink coffee every morning.
Finally, there is the word ”morgen” (note the small “m”) meaning “tomorrow”:
What are you doing tomorrow?
This word gives us a way to express “tomorrow morning”, namely ”morgen früh“:
Do you have time tomorrow morning?
(Better expressed as “Are you free tomorrow morning?” in English.) Perhaps to confuse the matters a little more at the end, it’s worth noting that “Morgen”, as a noun, can also be neuter, i.e. ”das Morgen”, which means “tomorrow” in the sense of “future”, for example:
For a better tomorrow.
Notice the neuter ending “-es” at the end of “besser”.